As I said, the guides method does work well. Of interest is that I tried the same thing using a different package, Corel PaintShop (I usually avoid anything Corel,) and got a surprise when I went to do the Shift-Drag. That itself does the draw from the centre without any other messing around. I guess it's more a paint thing rather than a photo processing thing although as much as nature abhors straight lines, it loves circles so I was surprised that photo processing wouldn't have it. But, as was explained, while nature loves circles, photos rarely will contain perfect circles and even if one does, the centre will not usually be conveniently marked.
Thanks to all for the explanations.