Thanks so much Kirk this has been a big help. I found the utility-linear-sRGB OCIO file applied as an adjustment layer has brought me back to what I see in both the Render frame buffer and photoshop and I've saved it as a preset for future use. I have also done a jpeg export test an it fairs pretty well, not a massive shift in the greens which is good. This might mean I can stay in linear space whilst editing which as you say is better but I have had experiences in the past where its tripped me up on export with colour and contrast shifts compared to keeping everything non linear sRGB.
So the next Q is - can I make that adjustment layer permanent for the whole stack of render passes that I have below this adjustment layer without flattening the stack? I can see issues cropping up with a mixing of converted and non converted layers getting mixed up above and below the adjustment layer which could be avoided if I could make the adjustment layer permanent instead of live.
Thanks again, you have been a big help.